144462-29-3

Basic information

• Product Name: Cyclohexanecarboxylic acid, 1-fluoro-2-oxo-, methyl ester, (R)-
• CAS NO: 144462-29-3
• Molecular Formula: C8H11FO3
• Molecular Weight: 174.172
• Mol File: 144462-29-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanecarboxylic acid, 1-fluoro-2-oxo-, methyl ester, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarboxylic acid, 1-fluoro-2-oxo-, methyl ester, (R)-(144462-29-3)
• EPA Substance Registry System: Cyclohexanecarboxylic acid, 1-fluoro-2-oxo-, methyl ester, (R)-(144462-29-3)

Safety Data

• Hazardous Substances Data: 144462-29-3(Hazardous Substances Data)

Upstream product

• 18709-01-8 cyclohexanone-2-carboxylic acid 
• 144462-26-0 C₁₇H₂₆O₃ 
• 41302-34-5 2-(methoxycarbonyl)cyclohexanone 
• 144462-36-2 C₁₇H₂₆F₂O₃ 

Downstream Products

• 144462-31-7 (S)-2-Fluoro-2-hydroxymethyl-cyclohexanone 
• 144462-30-6 (R)-1-Fluoro-2,2-dimethoxy-cyclohexanecarboxylic acid methyl ester 

Relevant articles and documents

Asymmetric fluorination of β-keto esters catalyzed by chiral rare earth perfluorinated organophosphates

Novel chiral rare earth metal complexes bearing perfluorinated binaphthyl phosphate ligand RE[(R)-F8BNP]3 (RE = rare earth; F8BNP = 5,5′,6,6′,7,7′,8,8′-octafluoro-1,1′-binaph thyl-2,2′-diyl phosphate) have been synthesized

A novel enantioselective preparation of α-fluoro-β-keto acids

A two-step method for the enantioselective preparation of α-fluorinated β-keto acids from 1,3-dioxin-4-ones having l-menthone as the chiral auxiliary at the 2-position is described. The method consists of fluorination of the dioxinones by molecular fluori