14447-07-5

Usage

Uses

Used in Polymer and Resin Production:
2-Butynedioic acid diallyl ester is used as a crosslinking agent for improving the properties of unsaturated polyester resins. It contributes to the formation of strong, durable materials with enhanced mechanical and chemical resistance.
Used in Adhesives and Sealants:
In the adhesive and sealant industry, 2-Butynedioic acid diallyl ester is used as an additive to improve the bonding strength and flexibility of the final products, ensuring better adhesion and durability.
Used in Coatings:
2-Butynedioic acid diallyl ester is utilized as a comonomer in the production of maleate-based polymers and copolymers for coatings. It enhances the flexibility and durability of the coatings, providing improved resistance to environmental factors and wear.
Environmental and Health Considerations:
While 2-Butynedioic acid diallyl ester offers significant benefits in various applications, it is crucial to handle this chemical with care due to its potential hazards to health and the environment if not used or disposed of properly. Proper safety measures and disposal methods should be adhered to in all applications involving 2-Butynedioic acid diallyl ester.

Upstream product

• 107-18-6 allyl alcohol 
• 142-45-0 Acetylenedicarboxylic acid 
• 675-75-2 1,4-Difluoro-2-butyne-1,4-dione 
• 19342-06-4 diallyl (E)-2,3-dibromobut-2-enedioate 

Downstream Products

• 83341-26-8 2-<4,5-Bis(allyloxycarbonyl)-1,3-dithiol-2-yliden>-3-(1,3-dibenzyl-2-imidazolidinyliden)butandisaeure-diallylester 

Relevant academic research and scientific papers

A 2- fluoro fumaric acid ester (formula I) and its preparation method and application

The invention discloses 2-fuloro fumarate (formula I) and a preparation method thereof. Experiments show that: the kinds of compounds are capable of effectively inhibiting NF-kB transcriptional activity introduced by TNF-alpha, and further are capable of treating diseases introduced by NF-kB, such as psoriasis, multiple sclerosis, arthritis, eye inflammation or allergy, asthma and lupus erythematosus, and can be used as an immunosuppressant for organ transplantation.

Aqueous-phase deactivation and intramolecular [2 + 2 + 2] cycloaddition of oxanorbornadiene esters

Both inter- and intramolecular degradation pathways were identified for the aqueous phase deactivation of oxanorbornadiene (OND) electrophiles, and propargylic OND esters were found to undergo facile intramolecular [2 + 2 + 2] homo-Diels-Alder cycloaddition in polar media.

Modular functionalization of carbon nanotubes and fullerenes

A series of highly efficient, modular zwitterion-mediated transformations have been developed which enable diverse functionalization of carbon nanotubes (CNTs, both single-walled and multi-walled) and fullerenes. Three functionalization strategies are demonstrated. (1) Trapping the charged zwitterion intermediate with added nucleophiles allows a variety of functional groups to be installed on the fullerenes and carbon nanotubes in a one-pot reaction. (2) Varying the electrophile from dimethyl acetylenedicarboxylate to other disubstituted esters provides CNTs functionalized with chloroethyl, allyl, and propargyl groups, which can further undergo SN2 substitution, thiol addition, or 1,3-dipolar cycloaddition reactions. (3) Postfunctionalization transformations on the cyclopentenones (e.g., demethylation and saponification) of the CNTs lead to demethylated or hydrolyzed products, with high solubility in water (1.2 mg/mL for MWCNTs). CNT aqueous dispersions of the latter derivatives arestable for months and have been successfully utilized in preparation of CNT-poly(ethylene oxide) nanocomposite via electrospinning. Large-scale MWCNT (10 g) functionalization has also been demonstrated to show the s calability of the zwitterion reaction. In total we present a detailed account of diverse CNT functionalization under mild conditions (60°C, no strong acids/bases, or high pressure) and with high efficiency (1 functional group per 10 carbon atoms for SWCNTs), which expand the utility of these materials.

Photochemical synthesis of prochiral dialkyl 3,3-dialkylcyclopropene-1,2-dicarboxylates with facial shielding substituents and related substrates

Different types of cyclopropene-1,2-dicarboxylates 1 have been obtained by photochemical methods from the corresponding pyrazoles 11, 12, or 13. These pyrazoles were synthesized by 1,3-dipolar cycloadditions of alkynes 8 or 9 with either preformed diazoalkanes or diazoalkanes generated photochemically in situ, by use of oxadiazolines as diazoalkane precursors. The numerous substrates have clearly established the scope and limitations of the syntheses of the precursors and the cyclopropenes by the different routes; even prochiral and enantiomerically pure chiral derivatives could be synthesized. Numerous precursors and cyclopropenes could be characterized by X-ray crystal structure analyses, which revealed interesting structural features and allowed unequivocal assignment of different diastereomers or constitutional isomers. Some of the photochemical reactions produced unique side-products; the crystal structure analyses were absolutely crucial for unambiguous structural assignment here. Wiley-VCH Verlag GmbH, 2001.