1445381-40-7

Upstream product

• 1445381-32-7 N-(tert-butyl)-2-((2-isopropyl-6-methylphenyl)amino)-2-methylpropanamide 
• 66875-78-3 2-bromo-N-(tert-butyl)-2-methylpropanamide 
• 1445381-37-2 N₁-(tert-butyl)-N₂-(2-isopropyl-6-methylphenyl)-2-methylpropane-1,2-diamine 

Relevant academic research and scientific papers

Synthesis of highly cis, syndiotactic polymers via ring-opening metathesis polymerization using ruthenium metathesis catalysts

The first example of ruthenium-mediated ring-opening metathesis polymerization generating highly cis, highly tactic polymers is reported. While the cis content varied from 62 to >95% depending on the monomer structure, many of the polymers synthesized displayed high tacticity (>95%). Polymerization of an enantiomerically pure 2,3-dicarboalkoxynorbornadiene revealed a syndiotactic microstructure.