144539-55-9Relevant academic research and scientific papers
Stereocontrolled Synthesis of Enantiomerically Pure 2-Dienyl Sulfoxides via Palladium-Catalyzed Coupling Reactions
Paley, Robert S.,Weers, Heather L.,Fernandez, Paloma
, p. 3605 - 3608 (2007/10/02)
Enantiopure 2-sulfinyl dienes can be prepared via regio- and stereoselective hydrostannylation of alkynylsulfoxides; after conversion to the corresponding vinyliodides these substrates may be coupled with vinylstannanes via Stille methodology in the prese
Optically active sulfoxides by enantiospecific reactions of bromovinyl aryl sulfoxides with grignard reagents
Cardellicchio, Cosimo,Fiandanese, Vito,Naso, Francesco,Scilimati, Antonio
, p. 5121 - 5124 (2007/10/02)
Optically active bromovinyl aryl sulfoxides were subjected to reactions with phenyl- or alkyl-magnesium compounds, with the production of optically active diaryl or aryl alkyl sulfoxides, with inversion of configuration. The enantiospecificity of the process was found to be 98-100%.
