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144542-93-8

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144542-93-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 144542-93-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,4,5,4 and 2 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 144542-93:
(8*1)+(7*4)+(6*4)+(5*5)+(4*4)+(3*2)+(2*9)+(1*3)=128
128 % 10 = 8
So 144542-93-8 is a valid CAS Registry Number.

144542-93-8Downstream Products

144542-93-8Relevant articles and documents

Dipivaloylketene and Its Dimers. versus Cycloaddition Reactions of α-Oxo Ketenes

Kappe, C. Oliver,Faerber, Gerald,Wentrup, Curt,Kollenz, Gert

, p. 7078 - 7083 (2007/10/02)

Dipivaloylketene (8) is generated by preparative flash vacuum pyrolysis of furandione 6.While dimerization of 8 in apolar and several polar solvents leads to the previously reported dimer 7, dimerization in the presence of DMSO, tributylphosphine oxide, or pyridine instead surprisingly occurs across the C=O bond of the ketene function, affording dioxinone 9.This is a novel type of α-oxo ketene dimerization.The reversibility of both dimerizations and mechanistic pathways for the formation of 9 are discussed.Cycloaddition reactions of 8 with heterocumulenes 10a,b and 12a-c yield cycloadducts 11a,b and 13a-c, respective ly.Oxazinones 13a-c can add a second molecule of 8 to generate novel spiro heterocycles 14a-c.In contrast, oxo ketene 7 reacts with carbodiimides 12a,b to furnish adducts 15a,b.This is the first unequivocal example of a direct cycloaddition reaction of an α-oxo ketene.The unexpected formation of these compounds was confirmed by X-ray crystallography (15a).General aspects of versus cycloaddition in α-oxo ketenes are discussed.

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