144573-41-1Relevant academic research and scientific papers
HETEROCYCLIZATION OF β,γ-DICHLORO KETONES AS A METHOD FOR THE SYNTHESIS OF FURAN DERIVATIVES
Mamedov, E. J.,Ismailov, A. G.,Kozhushkov, S. I.,Zefirov, N. S.
, p. 260 - 265 (2007/10/02)
Dichloro ketones obtained from acyl chlorides and allyl or β-methylallyl chloride undergo spontaneous cyclization to give 2-alkyl- and 2,4-dialkylfurans when they are heated; the intermediates in the case of 2,3-dichloropropene split out a molecule of hydrogen chloride to give 3,4-dichloro-2-butenones.
CHEMISTRY OF SYSTEMS OF THE ALLYLIC TYPE II. ACYLATION OF 3-BROMO- AND 2-METHYL-3-CHLORO-1-PROPENES
Ibragimov, I. I.,Mamedov, E. I.,Ismailov, A. T.,Aliev, A. G.,Mekhtieva, Sh. Z.,et al.
, p. 1425 - 1430 (2007/10/02)
The acylation of 3-bromo- and 2-methyl-3-chloro-1-propenes under the conditions of the Kondakov-Krapivin reaction showed that the addition of acyl chlorides to these compounds takes place according to the Markovnikov rule with formation of the corresponding halogen-containing α-β-unsaturated ketones and alkyl(cycloalkyl)furans.
