1445899-06-8

Basic information

• Product Name: 2-hydroxy-5-methylphenyl dimethylcarbamate
• Synonyms: 2-hydroxy-5-methylphenyl dimethylcarbamate
• CAS NO: 1445899-06-8
• Molecular Weight: 195.218
• Mol File: 1445899-06-8.mol

Chemical Properties

• CAS DataBase Reference: 2-hydroxy-5-methylphenyl dimethylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-hydroxy-5-methylphenyl dimethylcarbamate(1445899-06-8)
• EPA Substance Registry System: 2-hydroxy-5-methylphenyl dimethylcarbamate(1445899-06-8)

Safety Data

• Hazardous Substances Data: 1445899-06-8(Hazardous Substances Data)

Upstream product

• 108-39-4 3-methyl-phenol 
• 7305-07-9 m-tolyl dimethylcarbamate 

Relevant articles and documents

A general approach towards catechol and pyrogallol through ruthenium- and palladium-catalyzed C-H hydroxylation by weak coordination

An efficient ruthenium(II)- and palladium(II)-catalyzed C-H hydroxylation of aryl carbamates has been developed for the facile synthesis of catechols and pyrogallols. The reaction demonstrates excellent reactivity, regio- and chemoselectivity, good functional group compatibility and high yields. The practicality of this method has been proved by a gram-scale synthesis.

Ortho-and para-selective ruthenium-catalyzed C(sp2)-H oxygenations of phenol derivatives

Versatile ruthenium catalysts allowed for efficient direct oxygenations of aryl carbamates under remarkably mild reaction conditions. In addition to chelation-assisted C-H activation, the optimized ruthenium catalyst proved amenable to para-selective hydroxylations of anisoles without Lewis basic directing groups.