14459-59-7Relevant articles and documents
Butskii, V. D.,Ignatov, M. E.,Golovanov, B. V.
, (1985)
Reductive photo-chemical separation of the hexafluorides of uranium and molybdenum
Chemnitz, Tobias,Kraus, Florian,Petry, Winfried,Stene, Riane E.
supporting information, (2020/10/18)
Two new techniques are described for the separation of molybdenum hexafluoride (MoF6) from uranium hexafluoride (UF6). Both separation techniques utilize the differences displayed by the hexafluorides in their ability to absorb light in the near UV region. Because UF6 absorbs light in the near UV region and MoF6 does not, this observation was used to selectively reduce UF6 to uranium pentafluoride (UF5) through irradiation with 395 nm light in the presence of a suitable reducing agent. Two reducing agents were chosen for this study: gaseous, liquid, or super-critical carbon monoxide (CO) and liquid sulfur dioxide (SO2). Since MoF6 is not reduced under the reaction conditions described here, it may be removed via distillation from the uranium-containing sample after complete reduction of UF6 to solid UF5. The molybdenum- and uranium-containing samples were measured for purity through elemental analysis using microwave plasma atomic emission spectroscopy (MP-AES). Elemental analysis showed more than 98.8 % of the Mo had been removed from the U-containing samples. Further analyses of the samples were performed by X-ray powder diffraction and IR spectroscopy.
Separation of metallic residues from the dissolution of a high-burnup BWR fuel using nitrogen trifluoride
McNamara, Bruce K.,Buck, Edgar C.,Soderquist, Chuck Z.,Smith, Frances N.,Mausolf, Edward J.,Scheele, Randall D.
supporting information, p. 1 - 8 (2014/05/06)
Nitrogen trifluoride (NF3) was used to fluorinate the metallic residue from the dissolution of a high burnup, boiling water reactor fuel (～70 MWd/kgU). The washed residue included the noble-metal phase (containing ruthenium, rhodium, palladium, technetium, and molybdenum), smaller amounts of zirconium, selenium, tellurium, and silver, along with trace quantities of plutonium, uranium, cesium, cobalt, europium, and americium, likely as their oxides. Exposing the noble metal phase to 10% NF3 in argon, between 400 and 550 °C, removed molybdenum and technetium near 400 °C as their volatile fluorides, and ruthenium near 500 °C as its volatile fluoride. The events were thermally and temporally distinct and the conditions specified provide a recipe to separate these transition metals from each other and from the nonvolatile residue. Depletion of the volatile fluorides resulted in substantial exothermicity. Thermal excursion behavior was recorded with the thermal gravimetric instrument operated in a non-adiabatic, isothermal mode; conditions that typically minimize heat release. Physical characterization of the noble-metal phase and its thermal behavior are consistent with high kinetic velocity reactions encouraged by the nanoparticulate phase or perhaps catalytic influences of the mixed platinum metals with nearly pure phase structure. Post-fluorination, only two products were present in the residual nonvolatile fraction. These were identified as a nano-crystalline, metallic palladium cubic phase and a hexagonal rhodium trifluoride (RhF3) phase. The two phases were distinct as the sub-μm crystallites of metallic palladium were in contrast to the RhF3 phase, which grew from the parent, nano-crystalline noble-metal phase during fluorination, to acicular crystals exceeding 20-μm in length.
