144601-68-3Relevant academic research and scientific papers
Synthesis of O-alkylhydroxylamines by electrophilic amination of alkoxides
Foot, Oliver F.,Knight, David W.
, p. 975 - 976 (2007/10/03)
The 3-trichloromethyloxaziridine 7 reacts smoothly with lithium alkoxides, derived from a representative range of alcohols, transferring an NHBoc function to the oxygen to provide good to excellent yields of N-Boc-O- alkylhydroxylamines 8-16 by this new O-amination protocol.
Iron-mediated synthesis of t-butyl-N-(aryloxy)carbamates
Holden,Cole
, p. 2579 - 2586 (2007/10/02)
The anion of t-butyl-N-hydroxycarbamate displaces halogens from (η6-haloarene)(η5-cyclopentadienyliron) salts. The resulting complexes are demetallated by photolysis in sunlight to generate t-butyl-N-(aryloxy)carbamates.
