1446099-30-4

Basic information

• Product Name: tetrabutylammonium phenylphosphonofluoridodiselenoate
• CAS NO: 1446099-30-4
• Molecular Weight: 527.466
• Mol File: 1446099-30-4.mol

Chemical Properties

• CAS DataBase Reference: tetrabutylammonium phenylphosphonofluoridodiselenoate(CAS DataBase Reference)
• NIST Chemistry Reference: tetrabutylammonium phenylphosphonofluoridodiselenoate(1446099-30-4)
• EPA Substance Registry System: tetrabutylammonium phenylphosphonofluoridodiselenoate(1446099-30-4)

Safety Data

• Hazardous Substances Data: 1446099-30-4(Hazardous Substances Data)

Upstream product

• 429-41-4 tetrabutyl ammonium fluoride 
• 122039-27-4 woollins’ reagent 

Relevant articles and documents

Fluorinated phosphorus-selenium heteroatom compounds: Phenylphosphonofluorodiselenoic salts, adducts, and esters

2,4-Bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide, [PhP(Se)(μ-Se)]2, Woollins' reagent (WR), reacts with dry KF or tetrabutylammonium fluoride (TBAF) at room temperature generating the corresponding potassium and tetrabutylammonium phenyldiselenofluorophosphinates 1 and 2 in almost quantitative yields. Treating 1 with equimolar amounts of tetraphenylphosphonium chloride or 1,3-dimesityl-1H-imidazol-3-ium chloride in THF at room temperature afforded the corresponding organic adducts 3 and 4 in 90% and 87% yields. Reaction of 1 with mono- and dihalogenated alkanes gave a series of esters of phenylphosphonofluoridodiselenoates 5-8 and 9 in 79-93% yields. Two representative crystal structures are reported. Published 2013 by the American Chemical Society.