1446356-86-0Relevant academic research and scientific papers
Formation of bi-aryls via a domino palladium catalysis
Krishna,Gopi Krishna Reddy,Satyanarayana
, p. 861 - 864 (2015/03/05)
Synthesis of bi-aryls via a domino Pd-catalyzed reaction of 1-(2-bromophenyl)-2-methylpropan-1-ones/(2-bromophenyl)(cyclohexyl)methanones is presented. The mechanism of the reaction is believed to proceed through a five membered palladacycle that combines with a second molecule of halo-arene to yield the bi-aryls. This method is quite successful to deliver highly sterically crowded bi-aryls with dense functionalities on the aromatic rings.
Formation of bi-aryls via a domino palladium catalysis
Krishna,Reddy, A. Gopi Krishna,Satyanarayana
, p. 861 - 864 (2014/02/14)
Synthesis of bi-aryls via a domino Pd-catalyzed reaction of 1-(2-bromophenyl)-2-methylpropan-1-ones/(2-bromophenyl)(cyclohexyl)methanones is presented. The mechanism of the reaction is believed to proceed through a five membered palladacycle that combines with a second molecule of halo-arene to yield the bi-aryls. This method is quite successful to deliver highly sterically crowded bi-aryls with dense functionalities on the aromatic rings.
