1446757-51-2Relevant articles and documents
Synthesis of 1,2-phenylenedimethanols by base-promoted reduction of isobenzofuran-1(3H)-ones with silane
Liu, Bin,Zhou, Xigeng
, p. 725 - 728 (2019)
An efficient method for preparation of substituted 1,2-phenylenedimethanols and aliphatic 1,4-diols that are valuable intermediates in organic synthesis, has been developed by the base-promoted reduction of isobenzofuran-1(3H)-ones and γ-lactones with silane under mild conditions. Compared with traditional procedures using stoichiometric amounts of metal hydrides and alkyl reductants, the present method avoids the use of sensitive reagents and is operationally simple and a broad variety of functional groups are tolerated.
A synthetic O-methanol derivatives (by machine translation)
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Paragraph 0023, (2018/10/19)
The invention belongs to the technical field of chemical engineering, in particular to a synthetic O-methanol derivatives. The invention to phthalide as raw materials, alkali and under the effects of the compound silicane, through reducing the ring-opening reaction, to prepare the O-methanol. The method of the invention raw materials are easy, simple operation, strong reaction selectivity, high product yield, mild reaction conditions; synthetic mono substituted O b methanol derivatives high quality, functional group compatibility. (by machine translation)
