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144688-69-7

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144688-69-7 Usage

General Description

TERT-BUTYL 2-METHOXYPYRROLIDINE-1-CARBOXYLATE, also known as Tert-butyl 2-methoxypyrolidin-1-yl-carboxylate, is a chemical compound commonly used in the pharmaceutical industry. It is a pyrrolidine derivative with a tert-butyl ester group and a methoxy substituent. TERT-BUTYL 2-METHOXYPYRROLIDINE-1-CARBOXYLATE is often utilized as an intermediate for the synthesis of various pharmaceutical agents, particularly in the production of drugs and medication. TERT-BUTYL 2-METHOXYPYRROLIDINE-1-CARBOXYLATE has a wide range of applications and is a valuable building block for pharmaceutical research and development.

Check Digit Verification of cas no

The CAS Registry Mumber 144688-69-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,4,6,8 and 8 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 144688-69:
(8*1)+(7*4)+(6*4)+(5*6)+(4*8)+(3*8)+(2*6)+(1*9)=167
167 % 10 = 7
So 144688-69-7 is a valid CAS Registry Number.
InChI:InChI=1/C10H19NO3/c1-10(2,3)14-9(12)11-7-5-6-8(11)13-4/h8H,5-7H2,1-4H3

144688-69-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-butyl 2-methoxypyrrolidine-1-carboxylate

1.2 Other means of identification

Product number -
Other names N-Boc-2-methoxy-pyrrolidine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:144688-69-7 SDS

144688-69-7Relevant articles and documents

Paired Electrochemical Reactions and the On-Site Generation of a Chemical Reagent

Wu, Tiandi,Nguyen, Bichlien H.,Daugherty, Michael C.,Moeller, Kevin D.

, p. 3562 - 3565 (2019)

While the majority of reported paired electrochemical reactions involve carefully matched cathodic and anodic reactions, the precise matching of half reactions in an electrolysis cell is not generally necessary. During a constant current electrolysis almost any oxidation and reduction reaction can be paired, and in the presented work we capitalize on this observation by examining the coupling of anodic oxidation reactions with the production of hydrogen gas for use as a reagent in remote, Pd-catalyzed hydrogenation and hydrogenolysis reactions. To this end, an alcohol oxidation, an oxidative condensation, intramolecular anodic olefin coupling reactions, an amide oxidation, and a mediated oxidation were all shown to be compatible with the generation and use of hydrogen gas at the cathode. This pairing of an electrolysis reaction with the production of a chemical reagent or substrate has the potential to greatly expand the use of more energy efficient paired electrochemical reactions.

Expedient preparation of nazlinine and a small library of indole alkaloids using flow electrochemistry as an enabling technology

Kabeshov, Mikhail A.,Musio, Biagia,Murray, Philip R.D.,Browne, Duncan L.,Ley, Steven V.

supporting information, p. 4618 - 4621 (2015/01/08)

An expedient synthesis of the indole alkaloid nazlinine is reported. Judicious choice of flow electrochemistry as an enabling technology has permitted the rapid generation of a small library of unnatural relatives of this biologically active molecule. Furthermore, by conducting the key electrochemical Shono oxidation in a flow cell, the loading of electrolyte can be significantly reduced to 20 mol % while maintaining a stable, broadly applicable process.

Reactions of iminium ions with Michael acceptors through a Morita-Baylis-Hillman-type reaction: Enantiocontrol and applications in synthesis

Myers, Eddie L.,De Vries, Johannes G.,Aggarwal, Varinder K.

, p. 1893 - 1896 (2008/03/12)

(Chemical Equation Presented) All adducts one way: Iminium ions, generated in situ from the corresponding N,O-acetals, can be used as electrophiles in a Morita-Baylis-Hillman-type reaction with a wide range of Michael acceptors (enones, enals, S- and O-acrylates). The reaction has been rendered asymmetric using sulfide 1 (see scheme; DBU = 1,8-diazabicyclo[5.4.0]undec-7-ene, TMSOTf=trimethylsilyl trifluoromethanesulfonate).

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