1447447-05-3Relevant academic research and scientific papers
Room-temperature Suzuki-Miyaura cross-coupling reaction with α-diimine Pd(II) catalysts
Wang, Fuzhou,Tanaka, Ryo,Cai, Zhengguo,Nakayama, Yuushou,Shiono, Takeshi
, p. 771 - 776 (2015)
An α-diimine Pd(II) complex containing chiral sec-phenethyl groups, {bis[N,N′-(4-methyl-2-sec-phenethylphenyl)imino]-2,3-butadiene}dichloropalladium (rac-C1), was synthesized and characterized. rac-C1 was applied as an efficient catalyst for the Suzuki-Miyaura cross-coupling reaction between various aniline halides and arylboronic acid in PEG-400-H2O at room temperature. Among a series of aniline halides, rac-C1 did not catalyze the cross-coupling of aniline chlorides and fluorides but efficiently catalyzed the cross-coupling of aniline bromides and iodides with phenylboronic acid. The catalytic activity reduced slightly with increasing steric hindrance of the aniline bromides. The complexes {bis[N,N′-(4-fluoro-2,6-diphenylphenyl)imino]-2,3-butadiene}dichloropalladium and {bis[N,N′-(4-fluoro-2,6-diphenylphenyl)imino]acenaphthene}dichloropalladium were also found to be efficient catalysts for the reaction.
NOVEL COMPOUND AND ORGANIC LIGHT EMITTING DEVICE
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Paragraph 0158; 0171-0174; 0188-0192, (2020/11/11)
Novel compounds and organic light emitting devices are disclosed. The novel compound is represented by the following Chemical Formula 1, and when the novel compound is used as a material for a hole transport layer of an organic light emitting device, the
Nickel(II)-α-diimine complexes containing naphthyl substituents for ethylene polymerization under low ethylene pressure
Yuan, Jianchao,Jia, Zong,Li, Jing,Song, Fengying,Wang, Fuzhou,Yuan, Bingnian
, p. 341 - 350 (2013/06/05)
Two new α-diimine containing Ni(II) complexes, {bis[N,N′-(2,6- dimethyl-4-naphthylphenyl)imino]-1,2-dimethylethane}dibromonickel 3a and {bis[N,N′-(2-methyl-4-naphthylphenyl)imino]-1,2-dimethylethane} dibromonickel 3b were synthesized and characterized. Th
