14476-81-4Relevant academic research and scientific papers
Mechanism and Selectivity of Aryltrimethylgermane Cation Radical Fragmentations
Feinberg, Elizabeth C.,Dinnocenzo, Joseph P.
, p. 8639 - 8644 (2020)
Aryltrimethylgermane cation radicals were generated by nanosecond transient absorption spectroscopy. Transient kinetics experiments show that the aryltrimethylgermane cation radicals react with added nucleophiles in reactions that are first-order in both
Palladium-Catalyzed Germylation of Aryl Bromides and Aryl Triflates Using Hexamethyldigermane
Komami, Narumi,Matsuoka, Keitaro,Yoshino, Tatsuhiko,Matsunaga, Shigeki
, p. 2067 - 2075 (2018/02/26)
Palladium-catalyzed germylation of aryl bromides and aryl triflates using commercially available hexamethyldigermane is described. Optimized reaction conditions afforded various functionalized aryltrimethylgermanes, including drug-like molecules, in moderate to good yields, demonstrating the versatility of the presented protocols.
SYNTHESIS AND SPECTROSCOPIC CHARACTERISTICS OF ARYLTRIMETHYL-SILICON, -GERMANIUM, AND -TIN COMPOUNDS
Moerlein, S. M.
, p. 29 - 40 (2007/10/02)
The synthesis and spectroscopic characteristics of 28 para-substituted aryltrimethyl-silicon, -germanium, and -tin compounds are described.The infrared spectra show characteristic bands at 1245-1165 (methyl bend), 840-765 (methyl rock), and 1105-1020 (in-plane aromatic H bend) cm-1; the frequency of the last band was found to depend on the sum of the aromatic substituent masses, the presence or absence of metallic constituents in the substituent having little influence.The mass spectral fragmentation patterns are interpreted in terms of localization of positive charge on the metal atom, with subsequent bond cleavage behavior which obeys the rules for mass spectra of carbon compounds.
