1447669-03-5

Usage

Molecular structure

2,2'-((2,2-diphenylethene-1,1-diyl)bis(4,1-phenylene))bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) has a complex molecular structure consisting of two 2,2-diphenylethene-1,1-diyl units connected by a 4,1-phenylene linker, with each unit bonded to a 4,4,5,5-tetramethyl-1,3,2-dioxaborolane.

Synthesis

The compound is synthesized for various applications in organic chemistry and material science.

Applications

It is primarily used in the development of organic semiconductors and functional materials.

Intricate structure

The compound's complex molecular structure, featuring a unique arrangement of atoms and bonds, contributes to its potential applications in electronic and optical properties.

Boron-containing moieties

The presence of boron atoms in the compound makes it a valuable building block for the design and synthesis of novel organic molecules.

Potential electronic and optical properties

Due to its unique molecular structure and boron-containing moieties, the compound has potential electronic and optical properties that can be harnessed for various applications.

Upstream product

• 101-81-5 Diphenylmethane 
• 3988-03-2 bis(4-bromophenyl)methanone 
• 859315-37-0 1-bromo-4-(1-(4-bromophenyl)-2,2-diphenylvinyl)benzene 
• 73183-34-3 bis(pinacol)diborane 

Downstream Products

• 1569852-65-8 C₆₂H₄₆N₂ 
• 1447669-12-6 C₇₈H₅₆ 

Relevant academic research and scientific papers

Construction of efficient blue AIE emitters with triphenylamine and TPE moieties for non-doped OLEDs

In this paper, by merging the hole-dominated triphenylamine (TPA) and tetraphenylethene (TPE) moieties together with different linkage positions, four derivatives of 1,2-bis[4′-(diphenylamino)biphenyl-4-yl]-1,2- diphenylethene (2TPATPE) were successfully synthesized with confirmed structures, and their thermal, optical and electronic properties were fully investigated. Thanks to the introduction of the meta-linkage mode on the TPE core, their π-conjugation length could be effectively restricted to ensure blue emission. The non-doped OLEDs based on these four emitters exhibit blue emissions from 443-466 nm, largely blue-shifted with respect to the green emission of 2TPATPE (514 nm). Meanwhile, good electroluminescence efficiencies with Lmax, ηC,max, and ηP,max of up to 8160 cd m-2, 3.79 cd A-1, and 2.94 Im W-1 respectively, have also been obtained, further validating our rational design of blue AIE fluorophores. The Royal Society of Chemistry.

A new approach to prepare efficient blue AIE emitters for undoped OLEDs

Two aggregation-induced emission active luminogens (TPE-pTPA and TPE-mTPA) were successfully synthesized. For comparison, another six similar compounds were prepared. Because of the introduced hole-dominated triphenylamine (TPA), fluorene groups with high luminous efficiency, and unconjugated linkages, the π conjugation length of the obtained luminogens is effectively restricted to ensure their blue emission. The undoped organic light-emitting diodes based on TPE-pTPA and TPE-mTPA exhibited blue or deep-blue emissions, low turn-on voltages (3 V), and high electroluminescence efficiencies with Lmax, ηC,max, and ηP,max values of up to 26 697 cd m-2, 3.37 cd A-1, and 2.40 Lm W-1. By adding the hole-dominated triphenylamine (TPA) and fluorene groups with high luminous efficiency to the tetraphenylethene (TPE) moiety through unconjugated linkages, the π conjugation lengths of the fluorophores are effectively restricted to ensure deep-blue emission. Two of the undoped OLEDs exhibit blue and deep-blue emissions with good electroluminescence efficiencies.