14477-33-9Relevant academic research and scientific papers
Infrared and nuclear magnetic resonance spectra of hydroxytrimethylplatinum(IV)
Morgan, George L.,Rennick, Robert D.,Soong, Chia Chu
, p. 372 - 375 (1966)
An nmr method for determining the structure of tetrameric hydroxytrimethylplatinum by analyzing the hydroxylic proton resonance is reported. Mixed polymers of hydroxytrimethylplatinum and iodotrimethylplatinum have been detected in the nmr spectra, and interesting changes have been observed in JP1-C-H3. Both infrared and nmr evidence for hydrogen bonding of the hydroxylic proton have been obtained. A more complete infrared spectrum is reported in which all of the Pt-O and Pt-C vibration modes are identified. The unsymmetric CH3 deformation frequency is apparently split by Fermi resonance with an overtone of the Pt-O stretching frequency.
