144775-55-3Relevant academic research and scientific papers
Abnormal Reactions of Overcrowded Tris(arylchalcogeno)silyl Chlorides with Silver Perchlorate
Tokitoh, Norihiro,Imakubo, Tatsuro,Okazaki, Renji
, p. 5819 - 5822 (2007/10/02)
Sterically congested tris(arylchalcogeno)silyl chlorides were synthesized, and their reactions with silver perchlorate afforded unexpected products with a rearranged skeleton which were most likely formed via intermediary tris(arylchalcogeno)silicenium perchlorates.Key Words: silicenium ion; kinetic stabilization; rearrangement; tris(arylchalcogeno)silyl chloride; silver perchlorate
