144776-77-2

Upstream product

• 16169-82-7 (+/-)-3-acetyloxy-1-butyne 
• 201230-82-2 carbon monoxide 
• 766-77-8 Dimethylphenylsilane 
• 95314-73-1 methyl 1-methyl-2-propynyl carbonate 
• 128549-29-1 2-(1-hydroxyethyl)-3-dimethylphenylsilylpropenal 
• 2028-63-9 but-3-yn-2-ol 
• 144776-71-6 3-(N,N-dibenzyl)-aminobut-1-yne 
• 87065-03-0 Dibutyl-(1-methyl-prop-2-ynyl)-amine 

Relevant academic research and scientific papers

Rhodium-catalyzed transformation of propargyl alcohol derivatives to 2-silylmethyl-2-alkenals

Propargyl-type alcohols (6) and the corresponding esters of carbonic acid (4) or acetic acid (5) react with two equivalents of Me2PhSiH in the presence of catalytic amounts of Rh4(CO)12 under CO pressure at 100°C to give 2

Rhodium catalyzed transformation of propargylamines to 2-silylmethyl-2-alkenals: Formal silylformylation of allenes

Propargylamines are effectively transformed to 2-dimethylphenylsilylmethyl-2-alkenals by the interaction of two equivalents of Me2PhSiH under silylformylation conditions catalyzed by Rh4(CO)12. The products are not obtained directly by silylformylation of the corresponding allenes.