14478-07-0Relevant articles and documents
IR spectroscopic identification of electron attachment products of CCl4 in solid argon
Richter, Andreas,Meyer, Hermann,Mueller, Thomas,Specht, Harald,Schweig, Armin
, p. 359 - 366 (1997)
The electron attachment products of CCl4 due to photoinduced electron transfer (using the 4.88 eV photons of a Hg lamp) from N,N-dimethylaniline and N,N,N',N'-tetramethyl-p-phenylenediamine were investigated by FTIR spectroscopy in solid argon along with extensive ab initio calculations. Two attachment products have been detected by IR spectroscopy for the first time, i.e. the anions of CCl4 and CCl3, which are characterized by the complex structures Cl2CCl ··· Cl- and ClCCl ··· Cl-, respectively.
STUDY OF THE ALKALINE CLEAVAGE OF THE P-C BOND IN PHOSPHINE OXIDES AND DERIVATIVES OF TRICHLOROMETHANEPHOSPHONATE
Aksnes, Gunnar,Gierstae, Roald,Wulvik, Erik A.
, p. 141 - 152 (2007/10/02)
A study of alkaline decomposition of aromatic phosphine oxides containing p- and o-nitrobenzyl, and trichloromethyl as leaving groups, is reported.The property of the trichloromethyl group as leaving group, and the CCl3--group's further decomposition in the hydrolysis of diethyl and disodium trichloromethanephosphonates, have also been investigated.