1447829-22-2Relevant academic research and scientific papers
Regioselective copper-catalyzed carboxylation of allylboronates with carbon dioxide
Duong, Hung A.,Huleatt, Paul B.,Tan, Qian-Wen,Shuying, Eileen Lau
supporting information, p. 4034 - 4037 (2013/09/02)
In the presence of a Cu(I)/NHC catalyst, the reactions of allylboronic pinacol esters with CO2 (1 atm) are highly regioselective, giving exclusively the more substituted β,γ-unsaturated carboxylic acids in most cases. A diverse array of substituted carboxylic acids can be prepared via this method, including compounds featuring all-carbon quaternary centers.
