1447935-22-9Relevant academic research and scientific papers
Application of the 2-nitrobenzyl group in glycosylation reactions: A valuable example of an arming participating group
Buda, Szymon,Golebiowska, Patrycja,Mlynarski, Jacek
, p. 3988 - 3991 (2013)
The application of the o-nitrobenzyl (oNBn) group is demonstrated. This practical methodology allows the stereocontrolled synthesis of glucosides with a 1,2-trans linkage. This new ether-type arming group can broadly extend the concept of the use of participating groups in glycosylation reactions. Easy protection and deprotection of the oNBn group further confirms its usefulness in synthesis. The application of o-nitrobenzyl (oNBn) ether as an arming participating group is demonstrated. This practical methodology allows the stereocontrolled synthesis of glucosides with a 1,2-trans linkage. Copyright
