144796-50-9

Upstream product

• 402-31-3 1,3-bis(trifluoromethyl)benzene 
• 822-39-9 2-chloro-1,3,2-dioxaphospholan 

Downstream Products

• 15393-14-3 cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)] 
• 1210606-32-8 cis-[PtCl₂(2-(2,6-bis(trifluoromethyl)phenyl)-1,3,2-dioxaphospholane)(PPhMe₂)] 
• 1211095-41-8 trans-[PtCl₂(2-(2,6-bis(trifluoromethyl)phenyl)-1,3,2-dioxaphospholane)(PPhMe₂)] 
• 1210606-34-0 cis-[PtCl₂(2-(2,6-bis(trifluoromethyl)phenyl)-1,3,2-dioxaphospholane)2] 
• 1210606-31-7 cis-[PtCl₂(2-(2,6-bis(trifluoromethyl)phenyl)-1,3,2-dioxaphospholane)(PPh₂Me)] 
• 1210606-31-7 trans-[PtCl₂(2-(2,6-bis(trifluoromethyl)phenyl)-1,3,2-dioxaphospholane)(PPh₂Me)] 
• 1210606-33-9 cis-[PtCl₂(2-(2,6-bis(trifluoromethyl)phenyl)-1,3,2-dioxaphospholane)(PEt₃)] 
• 1210606-33-9 trans-[PtCl₂(2-(2,6-bis(trifluoromethyl)phenyl)-1,3,2-dioxaphospholane)(PEt₃)] 
• 1210606-30-6 cis-[PtCl₂(2-(2,6-bis(trifluoromethyl)phenyl)-1,3,2-dioxaphospholane)(PEt₃)] 
• 1210606-30-6 trans-[PtCl₂(2-(2,6-bis(trifluoromethyl)phenyl)-1,3,2-dioxaphospholane)(PEt₃)] 

Relevant academic research and scientific papers

The molecular structure of a 2-aryl-1,3,2-dioxaphospholane and its coordination behaviour towards platinum(II) species; molecular structures of four platinum(II) complexes

The molecular structure of the 2-aryl-1,3,2-dioxaphospholane, 2,6-(CF3)2-C6H3-P(OCH2)2 (1), has been determined by single-crystal X-ray diffraction at 120 K. Its reactions with the platinum

Metaphosphate intermediates from fluoroaromatic precursors

Flow pyrolysis of some 2-aryloxy-1,3,2-dioxaphospholanes with ortho-CF3 or F substituents, either alone or in the presence of methanol, has provided evidence for the formation of methaphosphates as intermediates; these highly reactive species then undergo further reaction, depending on the nature of the substituent.Mass spectrometric studies of the starting materials have also suggested the elimination of ethylene and the formation of methaphosphates to a limited extent.