1447963-73-6

Basic information

• Product Name: Palladacycle Gen. 3
• Synonyms: Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), 98%;Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),CPhos Palladacycle Gen. 3
• CAS NO: 1447963-73-6
• Molecular Formula: C41H54N3O3PPdS
• Molecular Weight: 806.35
• Product Categories: Buchwald Ligands&Precatalysts;Buchwald Precatalysts Series;Pd
• Mol File: 1447963-73-6.mol
• Article Data: 0

Chemical Properties

• Appearance: white to off-white/Powder
• CAS DataBase Reference: Palladacycle Gen. 3(CAS DataBase Reference)
• NIST Chemistry Reference: Palladacycle Gen. 3(1447963-73-6)
• EPA Substance Registry System: Palladacycle Gen. 3(1447963-73-6)

Safety Data

• Hazardous Substances Data: 1447963-73-6(Hazardous Substances Data)

Usage

Reactions

Catalyst for the highly selective cross-coupling of secondary alkylzinc reagents with heteroaryl halides Catalyst for the completely linear-selective Negishi cross-coupling of allylzinc halides with aryl and vinyl electrophiles

General Description

CPhos Pd G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.