1448068-07-2Relevant academic research and scientific papers
Robust cyclometallated Ir(iii) catalysts for the homogeneous hydrogenation of N-heterocycles under mild conditions
Wu, Jianjun,Barnard, Jonathan H.,Zhang, Yi,Talwar, Dinesh,Robertson, Craig M.,Xiao, Jianliang
supporting information, p. 7052 - 7054 (2013/09/02)
Cyclometallated Cp*Ir(N∧C)Cl complexes derived from N-aryl ketimines are highly active catalysts for the reduction of N-heterocycles under ambient conditions and 1 atm H2 pressure. The reaction tolerates a broad range of other potentially reducible functionalities and does not require the use of specialised equipment, additives or purified solvent.
