144809-33-6Relevant academic research and scientific papers
A fluorescent sensor for 2,3-bisphosphoglycerate using a europium tetra-N-oxide bis-bipyridine complex for both binding and signaling purposes
Best, Michael D.,Anslyn, Eric V.
, p. 51 - 57 (2003)
Host 1 was designed and synthesized as a fluorescent sensor for 2,3-bisphosphoglycerate (BPG, 3). The design features a tris-functionalized triethylbenzene core to preorganize binding groups. The three cationic moieties, a tetra-N-oxide bipyridine-europiu
Copper(I) and Silver(I) Homometallic Complexes of New Bis(2,2'-bipyridine) Ligands
Beer, Paul D.,Wheeler, John W.,Moore, Christopher P.
, p. 2667 - 2674 (2007/10/02)
New ligand systems containing two 2,2'-bipyridin-6-ylmethyl moieties linked via 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane, 1,4,10,13-tetrathia-7,16-diazacyclooctadecane, 4,4'-bipyridinediium, N,N',N''-tritosyldiethylenetriamine and toluene-p-sulfonamide spacer units have been prepared.A variety of homometallic copper(I) complexes have been isolated and fast atome bombardment mass spectrometry investigations suggest most of the complexes to be of general formula 2.Solution 1H NMR spectra of these species imply the existence of additional complex components of 1:1 L:copper(I) ratio.A variety of mono- and bi-metallic silver(I) complexes were also isolated with these ligands.
