144809-36-9

Basic information

• Product Name: [(1E)-8-bromooct-1-en-1-yl]benzene
• Synonyms: [(1E)-8-bromooct-1-en-1-yl]benzene
• CAS NO: 144809-36-9
• Molecular Weight: 267.209
• Mol File: 144809-36-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [(1E)-8-bromooct-1-en-1-yl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(1E)-8-bromooct-1-en-1-yl]benzene(144809-36-9)
• EPA Substance Registry System: [(1E)-8-bromooct-1-en-1-yl]benzene(144809-36-9)

Safety Data

• Hazardous Substances Data: 144809-36-9(Hazardous Substances Data)

Upstream product

• 85669-63-2 (E)-cinnamyl diethyl phosphate 
• 1119-51-3 bromopentene 
• 6783-05-7 trans-2-phenylvinylboronic acid 
• 103935-51-9 1-trifluoromethanesulfonyl-6-bromohexane 
• 536-74-3 phenylacetylene 
• 83947-56-2 4,4,5,5-tetramethyl-2-((E)-styryl)-[1,3,2]dioxaborolane 
• 129368-70-3 (6-bromohexyloxy)-tert-butyldimethylsilane 
• 4286-55-9 1-bromo-6-hexanol 
• 166115-18-0 2,2-dimethylpropionic acid 6-hydroxyhexyl ester 
• 629-11-8 1,6-hexanediol 

Relevant articles and documents

Mild Base Promoted Nucleophilic Substitution of Unactivated sp3-Carbon Electrophiles with Alkenylboronic Acids

Diverse alkenylboronic acids react smoothly with various sp3-carbon electrophiles such as unactivated alkyl triflates in the presence of mild bases such as K3PO4. The reaction protocol is very mild and thereby enables high functional group tolerance. This transition metal-free condition is orthogonal towards the classic transition metal catalyzed Suzuki coupling. (Figure presented.).

Copper-catalyzed allylic alkylations of alkylzirconium intermediates

Hydrozirconation of olefins followed by exposure of the resulting alkylzirconium species to catalytic CuCN in the presence of activated halides or phosphonates gives rise to products of aklkylation in good yields under mild conditions.