144823-68-7Relevant academic research and scientific papers
Silylzincation of carbon-carbon multiple bonds revisited
Auer, Gertrud,Oestreich, Martin
, p. 311 - 313 (2008/02/08)
The first investigation of the copper-catalyzed silylzincation of alkynes as well as a diene and styrene using bis(triorganosilyl) zinc reagents led to the development of an efficient procedure and the disclosure of an unexpected bissilylation and unfores
The synthesis of 3-trimethylsilyl-4-dimethyl(phenyl)silyl-but-3-en-2-one, a β-functionalised Michael acceptor
Fleming,Newton,Sabin,Zammattio
, p. 7793 - 7802 (2007/10/02)
The title compound 3 has been prepared by silyl-cupration of trimethylsilylacetylene followed by acetylation. The phenyldimethylsilyl group can be removed selectively in a three-step procedure to give 3-trimethylsilylbut-3-ene-2-one 1b. The enone 3 and cyclohexanone can be used in an annelation reaction to make 5-dimethyl(phenyl)silylbicyclo[4.4.0]decan-3-one 20 and hence to make 2-vinylcyclohexylacetic acid 23.
