1448312-44-4Relevant academic research and scientific papers
Synthesis and transformations of metallacycles 41.* Cyclomagnesiation of O-containing 1,2-dienes with Grignard reagents in the presence of Cp 2TiCl2
D'Yakonov,Makarov,Makarova,Khalilov,Dzhemilev
, p. 1943 - 1949 (2012)
A Cp2TiCl2-catalyzed intermolecular homocyclomagnesiation of O-containing 1,2-dienes and cross-cyclomagnesiation of O-containing 1,2-dienes with aliphatic 1,2-dienes of cyclic and acyclic structure have been accomplished using Grignard reagents, which led to mono- and bicyclic organomagnesium compounds in 61-94% yields.
