1448328-58-2

Basic information

• Product Name: (R)-4-(benzyloxy)-1-((2R,5S)-5-((S)-((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)(hydroxy)methyl)tetrahydrofuran-2-yl)butyl acetate
• Synonyms: (R)-4-(benzyloxy)-1-((2R,5S)-5-((S)-((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)(hydroxy)methyl)tetrahydrofuran-2-yl)butyl acetate
• CAS NO: 1448328-58-2
• Molecular Weight: 686.959
• Mol File: 1448328-58-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-4-(benzyloxy)-1-((2R,5S)-5-((S)-((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)(hydroxy)methyl)tetrahydrofuran-2-yl)butyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-(benzyloxy)-1-((2R,5S)-5-((S)-((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)(hydroxy)methyl)tetrahydrofuran-2-yl)butyl acetate(1448328-58-2)
• EPA Substance Registry System: (R)-4-(benzyloxy)-1-((2R,5S)-5-((S)-((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)(hydroxy)methyl)tetrahydrofuran-2-yl)butyl acetate(1448328-58-2)

Safety Data

• Hazardous Substances Data: 1448328-58-2(Hazardous Substances Data)

Upstream product

• 1448328-51-5 (5R)-5-((S)-1-((4-methoxybenzyl)oxy)but-3-yn-1-yl)-2,2,3,3,8,8,9,9-octamethyl-4,7-dioxa-3,8-disiladecane 
• 1448328-50-4 (2R,3S)-3-((4-methoxybenzyl)oxy)hex-5-yne-1,2-diol 
• 149859-05-2 1-[2',2'-dimethyl-(4'R)-1',3'-dioxolan-4'-yl]-(1S)-3-butyn-1-ol 
• 203913-56-8 (E)-8-(benzyloxy)oct-4-enal 
• 198411-03-9 (E)-8-(benzyloxy)oct-4-en-1-ol 
• 908864-33-5 (E)-oct-4-ene-1,8-diol 
• 53432-90-9 (E)-di-tert-butyl-4-octene-1,8-dioate 
• 1448328-57-1 (R)-4-(benzyloxy)-1-((2R,5S)-5-((S)-((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)(hydroxy)methyl)tetrahydrofuran-2-yl)butan-1-ol 
• 108-24-7 acetic anhydride 
• 1448328-56-0 (R)-4-(benzyloxy)-1-((2R,5S)-5-((S)-hydroxy((2R,4S,5R)-5-(hydroxymethyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)methyl)tetrahydrofuran-2-yl)butan-1-ol 
• 1448328-55-9 (2R,3S,5Z,7S,10E)-14-(benzyloxy)-3-((4-methoxybenzyl)oxy)-5-methyltetradeca-5,10-diene-1,2,7-triol 
• 1448328-54-8 (2R,3S,5Z,7S,10E)-14-(benzyloxy)-1,2-bis((tert-butyldimethylsilyl)oxy)-3-((4-methoxybenzyl)oxy)-5-methyltetradeca-5,10-dien-7-ol 
• 1448328-52-6 (2R,3S,7S,E)-14-(benzyloxy)-1,2-bis((tert-butyldimethylsilyl)oxy)-3-((4-methoxybenzyl)oxy)tetradec-10-en-5-yn-7-ol 

Downstream Products

• 1448328-60-6 (R)-1-((2R,5S)-5-((S)-((tert-butyldimethylsilyl)oxy)((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)methyl)tetrahydrofuran-2-yl)-4-hydroxybutyl acetate 
• 1448328-62-8 (1R,4S,5R)-6-((R)-4-benzyl-2-oxooxazolidin-3-yl)-1-((2R,5S)-5-((S)-((tert-butyldimethylsilyl)oxy)((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)methyl)tetrahydrofuran-2-yl)-4-hydroxy-5-methyl-6-oxohexyl acetate 
• 1448328-63-9 (1R,4S,5R)-6-((R)-4-benzyl-2-oxooxazolidin-3-yl)-1-((2R,5S)-5-((S)-((tert-butyldimethylsilyl)oxy)((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)methyl)tetrahydrofuran-2-yl)-5-methyl-6-oxo-4-((triethylsilyl)oxy)hexyl acetate 
• 1448328-64-0 (R)-4-benzyl-3-((2R,3S,6R)-6-((2R,5S)-5-((S)-((tert-butyldimethylsilyl)oxy)((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)methyl)tetrahydrofuran-2-yl)-6-hydroxy-2-methyl-3-((triethylsilyl)oxy)hexanoyl)oxazolidin-2-one 
• 1448328-65-1 (1R,4S,5R)-6-((R)-4-benzyl-2-oxooxazolidin-3-yl)-1-((2R,5S)-5-((S)-((tert-butyldimethylsilyl)oxy)((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)methyl)tetrahydrofuran-2-yl)-5-methyl-6-oxo-4-((triethylsilyl)oxy)hexyl chloromethanesulfonate 
• 1448328-66-2 (R)-4-benzyl-3-((R)-2-((2S,5S,7S)-2-((S)-((tert-butyldimethylsilyl)oxy)((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-hydroxy-2-methyltetrahydrofuran-2-yl)methyl)-1,6-dioxaspiro[4.5]decan-7-yl)propanoyl)oxazolidin-2-one 
• 1448328-69-5 (R)-4-benzyl-3-((R)-2-((2S,5S,7S)-2-((S)-((tert-butyldimethylsilyl)oxy)((2R,4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-((4-methoxybenzyl)oxy)-2-methyltetrahydrofuran-2-yl)methyl)-1,6-dioxaspiro[4.5]decan-7-yl)propanoyl)oxazolidin-2-one 
• 1448328-67-3 C₅₄H₉₁NO₁₁Si₃ 

Relevant articles and documents

Interplay of cascade oxidative cyclization and hydride shifts in the synthesis of the ABC spiroketal ring system of pectenotoxin-4

Concepts: The formation of stereochemically defined bis-THF units through a double cyclization and a hydride-shift-initiated route to spiroketals is described (see scheme; Xc=chiral auxiliary). The resulting sequence has been used in a synthesis of the C1-16 fragment of the naturally occurring antitumor agent pectenotoxin-4. Copyright