1448443-75-1Relevant academic research and scientific papers
Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides: Selective synthesis of carbocycle-fused fullerene monoadducts
Lu, Shirong,Si, Weili,Bao, Ming,Yamamoto, Yoshinori,Jin, Tienan
, p. 4030 - 4033 (2013/09/02)
An efficient and highly selective Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides for the synthesis of three-, five-, six-, and seven-membered carbocycle-fused fullerene monoadducts has been reported. The controlled experiments unambiguously disclosed that the reaction proceeds through the formation of a fullerene monoradical as a key intermediate.
