1448468-82-3Relevant academic research and scientific papers
Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines
Kumaran, Elumalai,How, Kai Tong Sonia,Ganguly, Rakesh,Li, Yongxin,Leong, Weng Kee
supporting information, p. 4149 - 4152 (2013/09/02)
The reaction of a terminal alkyne (RCCH) and 2-aminopyridine (R′C5NH3NH2) with the dinuclear species [Cp*IrCl2]2 afforded the cationic aminocarbene derivatives Cp*Ir(Cl)[ =C(CH2R)NHC5NH 3R′] via a hydroamination and a ligand substitution. The reaction pathway has been examined through computational studies.
