1448589-73-8

Basic information

• Product Name: ethyl (2E)-3-[(ethoxycarbonyl)amino]-2-nitro-3-(4-nitrophenyl)prop-2-enoate
• CAS NO: 1448589-73-8
• Molecular Weight: 353.288
• Mol File: 1448589-73-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl (2E)-3-[(ethoxycarbonyl)amino]-2-nitro-3-(4-nitrophenyl)prop-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (2E)-3-[(ethoxycarbonyl)amino]-2-nitro-3-(4-nitrophenyl)prop-2-enoate(1448589-73-8)
• EPA Substance Registry System: ethyl (2E)-3-[(ethoxycarbonyl)amino]-2-nitro-3-(4-nitrophenyl)prop-2-enoate(1448589-73-8)

Safety Data

• Hazardous Substances Data: 1448589-73-8(Hazardous Substances Data)

Upstream product

• 21646-74-2 1-nitro-2-(4-nitrophenyl)-1-ethoxycarbonylethene 
• 2955-74-0 ethyl N-{[(4-nitrobenzene)sulfonyl]oxy}carbamate 
• 78324-36-4 E-ethyl α-nitroβ-(4-nitrophenyl)acrylate 
• 78324-35-3 Z-ethyl α-nitro-β-(4-nitrophenyl)acrylate 

Relevant articles and documents

Selective amination reactions of α-nitro aryl and heteroaryl enoates

Highly functionalized tetrasubstituted alkenes were obtained by an unexpected amination reaction promoted by ethyl nosyloxycarbamate on various α-nitro aryl and heteroaryl enoates. A nitrene is likely the aminating species responsible for the observed insertion reaction leading to (E)-β-amino α-nitro enoates as the major products, regardless of the substrate configuration. The compounds, bearing two nitrogenous functional groups in different oxidation states, can be regarded as interesting synthons. In contrast, aziridination was observed for α-nitro alkyl enoates or β-nitro allylic alcohols.