1448675-82-8Relevant academic research and scientific papers
Asymmetric Pentafulvene Carbometalation - Access to Enantiopure Titanocene Dichlorides of Biological Relevance
Cini, Melchior,Bradshaw, Tracey D.,Woodward, Simon,Lewis, William
, p. 14179 - 14182 (2016/01/25)
Unprecedented asymmetric copper-catalyzed addition of ZnEt2 (ZnBu2) to the exocyclic C=C bond of pentafulvenes C5H4(=CHAr) (Ar=2-MeOPh and related species) results in enantiomerically enriched (up to 93:7 e.r.)
Cuprate addition to a 6-substituted pentafulvene - Preparation of sec-alkyl-substituted titanocene dichlorides and their biological activity
Cini, Melchior,Bradshaw, Tracey D.,Lewis, William,Woodward, Simon
, p. 3997 - 4007 (2013/07/26)
The copper-catalysed (10 mol-% CuBr·SMe2, CuCN·LiCl or CuI/PPh3) addition of RMgBr to the pentafulvene 1-(cyclopenta-2,4-dien-1-ylidenemethyl)-2-methoxybenzene allows the formation of cyclopentadienyl derivatives with α-CHR(2-MeOPh)
