1448725-04-9

Basic information

• Product Name: ethyl 5-methyl-4-phenyl-1-tosyl-1H-pyrrole-2-carboxylate
• Synonyms: ethyl 5-methyl-4-phenyl-1-tosyl-1H-pyrrole-2-carboxylate
• CAS NO: 1448725-04-9
• Molecular Weight: 383.468
• Mol File: 1448725-04-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 5-methyl-4-phenyl-1-tosyl-1H-pyrrole-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 5-methyl-4-phenyl-1-tosyl-1H-pyrrole-2-carboxylate(1448725-04-9)
• EPA Substance Registry System: ethyl 5-methyl-4-phenyl-1-tosyl-1H-pyrrole-2-carboxylate(1448725-04-9)

Safety Data

• Hazardous Substances Data: 1448725-04-9(Hazardous Substances Data)

Upstream product

• 24037-94-3 2-Phenyl-1-buten-3-on-oxim-methylaether 
• 83670-53-5 (E)-ethyl 2-(tosylimino)acetate 

Relevant articles and documents

Rhodium(III)-catalyzed alkenyl C-H bond functionalization: Convergent synthesis of furans and pyrroles

Ring in the new: A new annulation for the efficient synthesis of substituted furans and pyrroles is reported. The RhIII-catalyzed reaction of O-methyl α,β-unsaturated oximes with aldehydes and N-tosyl imines affords secondary alcohol and amine intermediates, respectively. Cyclization and aromatization occurs under the reaction conditions to provide access to biologically relevant furans and pyrroles in good yields. Cp=C5Me5, DCE=1,2-dichloroethane, THF=tetrahydrofuran. Copyright