144882-72-4Relevant academic research and scientific papers
ETHYLMAGNESIUM BROMIDE MEDIATED DESULFINYLATION OF α-HALO-β-KETOSULFOXIDES GIVING α-HALOKETONES, AND TRAPPING OF THE MAGNESIUM ENOLATE INTERMEDIATE
Satoh, Tsuyoshi,Onda, Ken-ichi,Itoh, Norifumi,Yamakawa, Koji
, p. 5599 - 5600 (2007/10/02)
Treatment of α-halo-β-ketosulfoxides with EtMgBr gives α-haloketones in high yields after protonation of the magnesium enolates.Trapping of the magnesium enolates with various electrophiles is also carried out.
