1448839-03-9Relevant academic research and scientific papers
Synthesis, x-ray crystal structure, and oxidation catalytic property of a dioxomolybdenum(VI) complex derived from 5-diethylamino-2-[(2-hydroxyethylimino) methyl]phenol
Ding, Shao-Bing
, p. 877 - 881 (2013)
A new dioxomolybdenum(VI) complex, [MoO2L(CH3OH)], where L is the dianion of 5-diethylamino-2-[(2-hydroxyethylimino) methyl]phenol, was prepared and structurally characterized by physicochemical and spectroscopic methods and single-crystal X-ray determination. The Mo atom in the complex is in octahedral coordination. The crystal of the complex is stabilized by hydrogen bonds. The complex functions as an effective olefin epoxidation catalyst with hydrogen peroxide as terminal oxidant and sodium hydrogen carbonate as a cocatalyst under air atmosphere at room temperature.
