1448846-99-8Relevant academic research and scientific papers
Asymmetric hydrogenation of α,α′-disubstituted cycloketones through dynamic kinetic resolution: An efficient construction of chiral diols with three contiguous stereocenters
Liu, Chong,Xie, Jian-Hua,Li, Ya-Li,Chen, Ji-Qiang,Zhou, Qi-Lin
, p. 593 - 596 (2013/02/23)
Chiral diols with three contiguous stereocenters were synthesized by a highly enantioselective ruthenium-catalyzed asymmetric hydrogenation of racemic α,α′-disubstituted cycloketones involving dynamic kinetic resolution. This new catalytic asymmetric method provides a concise route to the alkaloid (+)-γ-lycorane. Copyright
