1448853-58-4Relevant academic research and scientific papers
Stereoselective synthesis of 2-substituted 1-iodo-1,3-dienes by the addition of MeMgSnBu3 to the conjugated terminal enynes; stereocontrolled synthesis of (2E,4Z,6E)-dehydrodendrolasin
Kawahama, Reiko,Uenishi, Jun'ichi
, p. 649 - 658 (2012)
Addition of MeMgSnBu3 to the conjugated enynes 1 and 5 were thoroughly studied. The addition reactions were proceeded stereoselectively at -20 °C, but a thermal isomerization occurred when the reaction was carried out at 0 °C. (2E,4Z,6E)-Dehydr
