1448894-58-3Relevant academic research and scientific papers
Redox-regulated rotary motion of a bis(9-triptycyl)-TTFV system
Chen, Guang,Zhao, Yuming
, p. 668 - 671 (2014)
A tetrathiafulvalene vinylogue (TTFV) unit was covalently linked to two benzyltriptycene molecular rotors to form a molecular gearset. Dynamic NMR studies showed that reversible redox reactions at the TTFV central unit exerted regulation over the rotational properties of the 9-triptycyl rotors.
Synthesis and properties of tetrathiafulvalenes bearing 6-aryl-1,4-dithiafulvenes
Itou, Toshiki,Kagawa, Kohei,Kimura, Hitoshi,Misaki, Yohji,Shirahata, Takashi,Vasu, Dhananjayan,Yorimitsu, Hideki,Yoshimura, Aya,Yoshioka, Mayuka
supporting information, p. 974 - 981 (2020/07/04)
Novel multistage redox tetrathiafulvalenes (TTFs) bearing 6-aryl-1,4-dithiafulvene moieties were synthesized by palladium-catalyzed direct C-H arylation. In the presence of a catalytic amount of Pd(OAc)2, P(t-Bu3)·HBF4, and an excess of Cs2CO3, the C-H arylation of TTF with several aryl bromides bearing 1,3-dithiol-2-ylidenes took place efficiently to produce the corresponding p-conjugated molecules. We also succeeded in the estimation of the oxidation potentials and number of electrons involved in each oxidation step of the obtained compounds by digital simulations.
Bromophenyl substituted dithiafulvenes and tetrathiafulvalene vinylogues: Synthesis, structure, and electronic properties
Bouzan, Stephen,Dawe, Louise N.,Zhao, Yuming
supporting information, p. 4666 - 4669 (2013/08/23)
Bis(bromophenyl) substituted tetrathiafulvalene vinylogues (TTFVs) were prepared via oxidative dimerization reactions of corresponding bromophenyl substituted dithiafulvene precursors. The synthesis of ortho-bromophenyl TTFVs led to the formation of an un
