1448902-17-7

Basic information

• Product Name: C₁₂H₂₂P₅⁽¹⁺⁾*Cl₄Ga^(1-)
• Synonyms: C₁₂H₂₂P₅⁽¹⁺⁾*Cl₄Ga^(1-)
• CAS NO: 1448902-17-7
• Molecular Weight: 532.71
• Mol File: 1448902-17-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₂H₂₂P₅⁽¹⁺⁾*Cl₄Ga^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₂H₂₂P₅⁽¹⁺⁾*Cl₄Ga^(1-)(1448902-17-7)
• EPA Substance Registry System: C₁₂H₂₂P₅⁽¹⁺⁾*Cl₄Ga^(1-)(1448902-17-7)

Safety Data

• Hazardous Substances Data: 1448902-17-7(Hazardous Substances Data)

Upstream product

• 16523-54-9 chlorodicyclohexylphosphane 

Downstream Products

• 1314-85-8 phosphorus sulfide 
• 1448902-39-3 Cl₄Ga^(1-)*C₁₂H₂₂P₅S₂⁽¹⁺⁾ 
• 1448902-34-8 Cl₄Ga^(1-)*C₁₂H₂₂P₅Se₂⁽¹⁺⁾ 

Relevant articles and documents

Synthesis of cationic R2P5+ cages and subsequent chalcogenation reactions

Cationic R2P5+ cage compounds (1 +) have been synthesized by the stoichiometric reaction of R 2PCl, GaCl3 and P4. The reaction conditions depend on the substituent R. Alkyl-substituted derivatives (1 a-1 d[GaCl 4]) are best synthesized under solvent-free conditions, whereas aryl-substituted derivatives (1 e-1 h[GaCl4]) are formed in C 6H5F. All compounds have been prepared on a multi-gram scale in good to excellent yields and have been fully characterized with an emphasis on 31P NMR spectroscopy in solution and single-crystal structure determination. Subsequent chalcogenation reactions of cations R 2P5+ (1 a+, 1 e+) and trication Ph6P73+ (33+) with elemental sulfur (α-S8) or grey selenium (Segrey) yielded a series of unique polyphosphorus-chalcogen cations (4 a+, 4 e+, 5 a+, 62+ and 72+ Copyright