1449017-78-0

Basic information

• Product Name: benzyl 2-tert-butoxycarbonyl-4,6-O-benzylidene-2-deoxy-3-O-[(R)-1-(methoxycarbonyl)ethyl]-α-D-glucopyranoside
• Synonyms: benzyl 2-tert-butoxycarbonyl-4,6-O-benzylidene-2-deoxy-3-O-[(R)-1-(methoxycarbonyl)ethyl]-α-D-glucopyranoside
• CAS NO: 1449017-78-0
• Molecular Weight: 543.614
• Mol File: 1449017-78-0.mol

Chemical Properties

• CAS DataBase Reference: benzyl 2-tert-butoxycarbonyl-4,6-O-benzylidene-2-deoxy-3-O-[(R)-1-(methoxycarbonyl)ethyl]-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 2-tert-butoxycarbonyl-4,6-O-benzylidene-2-deoxy-3-O-[(R)-1-(methoxycarbonyl)ethyl]-α-D-glucopyranoside(1449017-78-0)
• EPA Substance Registry System: benzyl 2-tert-butoxycarbonyl-4,6-O-benzylidene-2-deoxy-3-O-[(R)-1-(methoxycarbonyl)ethyl]-α-D-glucopyranoside(1449017-78-0)

Safety Data

• Hazardous Substances Data: 1449017-78-0(Hazardous Substances Data)

Relevant articles and documents

Novel fully protected muramic acid: A facile synthesis and structural study

Synthesis and structural characterisation of novel fully protected muramic acid 2 (N-Boc-Mur-OMe, Mur = muramic acid) has been reported. N-Ac-Mur-OMe (1) prepared starting from commercially available N-acetylglucosamine, was treated with di-tert-butyl dicarbonate (Boc2O) and N, N-dimethyl-4- aminopyridine (DMAP) in tetrahydrofuran. The intermediate mixed imide N-Ac-N-Boc-Mur-OMe was converted to N-Boc-Mur-OMe (2) upon in situ treatment with hydrazine hydrate in methanol. The structural analysis of 2, performed by IR and NMR spectroscopic methods and X-ray crystallography, was augmented by computational calculations including molecular and density functional theory studies (DFT) using M06/6-31G(d) computational model. The spectroscopic and DFT data obtained for novel Boc-protected 2 were compared with corresponding experimental values of its previously described Ac-protected analogue 1 in order to examine if the replacement of the protecting groups influences the conformational properties.