144918-33-2Relevant academic research and scientific papers
A Convenient Synthesis of (E)-β-Ethoxycarbonylvinylsilanes by Palladium-catalysed Regio- and Stereo-specific Hydroesterification of Trimethylsilylacetylenes
Takeuchi, Ryo,Sugiura, Masaharu,Ishii, Naomi,Sato, Nobuhiro
, p. 1358 - 1359 (1992)
Palladium-catalysed hydroesterification of trimethylsilylacetylenes 1 gives (E)-β-ethoxycarbonylvinylsilanes 2 exclusively in excellent yields.
A Novel and Stereodefined Synthesis of (E)-β-Ethoxycarbonylvinylsilanes: Regio- and Stereo-controlled Hydroethoxycarbonylation of Silylacetylenes by Palladium(II) Catalysis
Takeuchi, Ryo,Sugiura, Masaharu
, p. 1031 - 1038 (2007/10/02)
-SnCl2*2H2O catalysed hydroethoxycarbonylation of silylacetylenes 1 provided a novel and convenient synthesis of (E)-β-ethoxycarbonylvinylsilanes 2.The reactions, carried out under mild conditions (90 deg C, 20 kg cm-2) gave the pr
