1449307-65-6Relevant articles and documents
Direct vicinal disubstitution of diaryliodonium salts by pyridine N-oxides and N-amidates by a 1,3-radical rearrangement
Peng, Jing,Chen, Chao,Wang, Yong,Lou, Zhenbang,Li, Ming,Xi, Chanjuan,Chen, Hui
supporting information, p. 7574 - 7578 (2013/07/26)
Paired off: The title reaction leads to a series of o-pyridinium phenols (1) and anilines (2). The experimental and computational studies indicate that the key step involves homolytic cleavage to give a radical pair, which undergoes solvent-cage recombination to give the product. Copyright