1449332-48-2Relevant articles and documents
Cobalt-catalyzed hydrosilation/hydrogen-transfer cascade reaction: A new route to silyl enol ethers
Lyons, Thomas W.,Brookhart, Maurice
supporting information, p. 10124 - 10127 (2013/09/02)
Capitalizing on cobalt: A new route to silyl enol ethers employing a Co-catalyzed cascade reaction featuring a tandem hydrosilation/hydrogen-transfer reaction is reported. The low catalyst loading, mild reaction conditions, and unique η2-silane resting state showcase the impressive utility of this seldom used transition-metal catalyst in C-H activation reactions (see scheme; VTMS = vinyltrimethylsilane; Cp* = 1,2,3,4,5- pentamethylcyclopentadiene). Copyright
