1449374-96-2

Upstream product

• 1449374-89-3 (2R,3S,4R,5S,6R)-2-(2-methylprop-1-en-1-yl)-6-((tert-butyldiphenylsilyloxy)methyl)tetrahydro-2H-pyran-3,4,5-triol 
• 4163-65-9 per-O-acetyl-α-D-mannopyranose 
• 13242-53-0 acetobromomannose 
• 1449374-88-2 (2R,3S,4R,5S,6R)-2-(hydroxymethyl)-6-(2-methylprop-1-en-1-yl)tetrahydro-2H-pyran-3,4,5-triol 
• 1449374-95-1 tert-butyl(((3aS,4R,6S,7aS)-4-((E)-3-(4-methoxybenzyloxy)prop-1-en-1-yl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-6-yl)methoxy)diphenylsilane 
• 1449374-94-0 (E)-3-((3aS,4R,6S,7aS)-6-((tert-butyldiphenylsilyloxy)methyl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-4-yl)prop-2-en-1-ol 
• 1449374-93-9 (E)-ethyl 3-((3aS,4R,6S,7aS)-6-((tert-butyldiphenylsilyloxy)methyl)-2,2-dimethyl-tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-4-yl)acrylate 
• 1449374-92-8 tert-butyl(((3aS,4R,6S,7aS)-2,2-dimethyl-4-(2-methylprop-1-en-1-yl)tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-6-yl)methoxy)diphenylsilane 
• 1449374-91-7 O-((3aR,4R,6R,7R,7aR)-6-((tert-butyldiphenylsilyloxy)methyl)-2,2-dimethyl-4-(2-methylprop-1-en-1-yl)tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-7-yl)-S-methyl carbonodithioate 
• 1449374-90-6 (3aR,4R,6R,7R,7aS)-6-((tert-butyldiphenylsilyloxy)methyl)-2,2-dimethyl-4-(2-methyl-prop-1-en-1-yl)tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-7-ol 
• 1414849-31-2 (2R,3R,4R,5R,6R)-2-(acetoxymethyl)-6-(2-methylprop-1-en-1-yl)tetrahydro-2H-pyran-3,4,5-triyl triacetate 

Downstream Products

• 1449374-98-4 tert-butyl(((3aS,4S,6S,7aS)-4-((4R,5S)-5-((4-methoxybenzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-6-yl)methoxy)diphenylsilane 
• 1449375-00-1 C₂₃H₃₂O₈ 
• 1449375-03-4 (R)-1-((3aS,4S,6S,7aS)-4-((4R,5S)-5-((4-methoxybenzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-6-yl)ethane-1,2-diol 
• 1449375-04-5 C₂₄H₃₄O₈ 
• 1449375-05-6 C₃₀H₄₈O₈Si 
• 1449374-99-5 ((3aS,4S,6S,7aS)-4-(5-((4R,5S)-(4-methoxybenzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-6-yl)methanol 
• 1449375-01-2 (3aS,4S,6S,7aS)-4-((4R,5S)-5-((4-methoxybenzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyl-6-vinyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran 
• 1449375-02-3 (S)-1-((3aS,4S,6S,7aS)-4-((4R,5S)-5-((4-methoxybenzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-6-yl)ethane-1,2-diol 
• 1449375-06-7 tert-butyl(((S)-1-((3aS,4S,6S,7aS)-4-((4R,5S)-5-((4-methoxybenzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-6-yl)-4-(trimethylsilyl)pent-4-en-1-yl)oxy)dimethylsilane 

Relevant academic research and scientific papers

Iron-catalyzed cross-coupling between C-bromo mannopyranoside derivatives and a vinyl Grignard reagent: Toward the synthesis of the C31-C52 fragment of amphidinol 3

A chemo- and diastereoselective iron-catalyzed cross-coupling between C-bromo mannopyranoside derivatives and 2-methyl-1-propenylmagnesium bromide was developed. This method was used as the key step for the synthesis of the mirror image of the C31-C40 and