1449412-84-3Relevant academic research and scientific papers
Desymmetrization of 4,6-diprotected myo-inositol
Lauber, Markus B.,Daniliuc, Constantin-Gabriel,Paradies, Jan
supporting information, p. 7409 - 7411 (2013/09/23)
The asymmetric desymmetrization of 4,6-diprotected myo-inositol derivatives was achieved by using a bifunctional, readily available nucleophilic catalyst. The orthogonally protected products were obtained in 80-99% yield with 90-99% ee. Such structures serve as potential enantiopure building blocks for the synthesis of myo-inositol phosphates.
