1449549-24-9Relevant articles and documents
Pd-catalyzed addition of boronic acids to ynol ethers: A highly regio- and stereoselective synthesis of trisubstituted vinyl ethers
Bai, Yihui,Yin, Jing,Kong, Wei,Mao, Mengyi,Zhu, Gangguo
supporting information, p. 7650 - 7652 (2013/09/02)
A Pd-catalyzed addition of boronic acids to ynol ethers has been realized, delivering trisubstituted vinyl ethers in good yields with perfect control of the regio- and stereoselectivity. The reaction proceeds under mild conditions and exhibits excellent functional group compatibility. Moreover, the resultant products can be converted into pentasubstituted benzenes via the tandem Diels-Alder/aromatization reaction. The Royal Society of Chemistry.