1449550-75-7Relevant academic research and scientific papers
Reversible insertion of unactivated alkenes into silicon(II)-tin bonds
Rodriguez, Ricardo,Contie, Yohan,Gau, David,Saffon-Merceron, Nathalie,Miqueu, Karinne,Sotiropoulos, Jean-Marc,Baceiredo, Antoine,Kato, Tsuyoshi
, p. 8437 - 8440 (2013)
Insertion without assertion: Alkenes reacted reversibly under mild conditions (25-85 °C) with phosphine-silylene complexes containing a Si II-Sn bond to give alkyl silylene complexes (see scheme). Theoretical studies indicated that the insertion reaction proceeds through oxidative addition and migratory insertion in a two-step process and thus revealed that silicon(II)-phosphine complexes can behave like transition-metal complexes. Copyright
