1449612-30-9Relevant articles and documents
Palladium-catalyzed selective fluorination of o-carboranes
Qiu, Zaozao,Quan, Yangjian,Xie, Zuowei
, p. 12192 - 12195 (2013)
A Pd(II)-catalyzed direct selective fluorination reaction of carboranes using a F+ reagent has been developed, leading to a series of polyfluorocarboranes in high isolated yields. The mechanism involving electrophilic B-H activation, oxidation of Pd(II) by F+ species, and reductive elimination is proposed.